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Item Build:
Consider opting for a Ring of Aquilas and a Magick Stick instead of 2x Wraith Bands. RoA builds out of a Wraith Band + Ring of Basilus and is an extremely good item for ranged AGI heroes like Viper, providing DPS, bulk and a bit of Mana regen for Poison Attack. Magic Stick is a strong option because it builds out of 3x Branches and has an exceptionally useful active for its cost.
Thanks to Corrosive Skin, Radiance is an interesting choice on Viper, but your build timing is off. Radiance is not a late-game item; instead, as a source of constant, flat AoE magic damage, it is more effective the earlier you get it. If you are going to get Radiance on Viper, you should get it early/mid game, preferably if you are snowballing hard.
Shadow Blade/Manta Style/Monkey King Bar is a nice core, however. Butterfly/Heart/Assault Cuirass make excellent luxuries in games that just won't end. Don't forget to tell people to carry TP Scrolls as well; TPs are very important for Viper for both counter ganking/possibly escaping ganks.
Skill Build:
Your skill build is a bit scattered; I prefer:
Q/W/Q/E/Q/R/W/W/W/E/R/E/E/Q/Stats/R
Poison Attack is rushed but left at Rank 3 due to it's linear damage/slow scaling and cooldown scaling of 4/3/0/0. Nethertoxin is maxed first over Corrosive Skin due to it's stronger scaling per point (32/64/96/128 versus 10/15/20/25%). A rank of Corrosive Skin is taken at Level 2/4 to take advantage of it's Rank 1 strength.